catena-Poly[[[1,2-bis(benzimidazol-2-yl)ethane]cadmium(II)]-μ-sebacato]
نویسندگان
چکیده
In the title compound, [Cd(C(10)H(16)O(4))(C(16)H(14)N(4))](n), the Cd(II) ion is six-coordinated in a distorted octa-hedral geometry by four carboxyl-ate O atoms from two sebacate ligands and two N atoms from the chelating 1,4-bis-(2-benzimidazol-yl)ethanebutane ligand. Neighboring Cd(II) ions are bridged by the sebacate ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra-molecular structure through inter-molecular N-H⋯O hydrogen bonds.
منابع مشابه
catena-Poly[[(acetato-κ2 O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ2 N 3:N 3′-[(acetato-κ2 O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido]
In the title complex, [Cd(2)(CH(3)COO)(2)Cl(2)(C(16)H(14)N(4))(CH(3)OH)(2)](n), the Cd(II) atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis-(2,2'-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol mol-ecule and two bridging Cl atoms in a distorted octa-hedral geometry. The Cd(II) atoms are connected alte...
متن کاملA coordination polymer of CdII with benzene-1,3-dicarboxylate and 1,4-bis[1-(2-pyridylmethyl)benzimidazol-2-yl]butane
The title Cd(II) coordination polymer, catena-poly[[{1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane}cadmium(II)]-μ-benzene-1,3-dicarboxyl-ato], [Cd(C(8)H(4)O(4))(C(30)H(28)N(6))](n), was obtained by reaction of CdCO(3), benzene-1,3-dicarboxylic acid (H(2)btc) and 1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane (L). The Cd(II) cation is six-coordinated by an N(2)O(4)-donor set. L ac...
متن کاملcatena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ2 N:N′] 1,2-bis(pyridin-4-yl)ethane monosolvate]
The reaction of manganese seleno-cyanate with 1,2-bis-(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)2(C12H12N2)(CH3OH)2]·C12H12N2} n . The Mn(II) cation is coordinated by two N-bonded seleno-cyanate anions, two bpa ligands and two O-bonded methanol mol-ecules, within a slightly distorted octa-hedral geometry. The Mn(II) cations and the non-coordinating N-donor ligands are lo...
متن کاملcatena-Poly[[[diaquabis(selenocyanato-κN)iron(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ2 N:N′] 1,2-bis(pyridin-4-yl)ethane disolvate dihydrate]
The title compound, {[Fe(NCSe)2(C12H12N2)(H2O)2]·2C12H12N2·2H2O} n , was obtained by the reaction of iron(II) sulfate hepta-hydrate and potassium seleno-cyanate with 1,2-bis-(pyridin-4-yl)ethane (bpa) in water. The Fe(II) cation is coordinated by two N-bonded seleno-cyanate anions, two water mol-ecules and two 1,2-bis-(pyridin-4-yl)ethane (bpa) ligands in a slightly distorted octa-hedral geomet...
متن کاملcatena-Poly[[[(acetato-κ2 O,O′)cadmium]-μ-acetato-κ3 O,O′:O′-μ-{1,2-bis[4-(pyridin-3-yl)pyrimidin-2-ylsulfanyl]ethane}-κ2 N 4,N 4′] trihydrate]
The title compound, {[Cd(CH(3)COO)(2)(C(20)H(16)N(6)S(2))]·3H(2)O}(n), exists as a one-dimensional zigzag polymer in which the Cd(II) ion shows a seven-coordinate [CdO(5)N(2)] distorted penta-gonal-bipyramidal geometry with the N atoms in axial positions and an N-Cd-N angle of 176.94 (13)°. The metal atoms are bridged by 1,2-bis-[4-(pyridin-3-yl)pyrimidin-2-ylsulfan-yl]ethane ligands, giving a ...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010